1289 0 obj <>/Filter/FlateDecode/ID[]/Index[1273 31]/Info 1272 0 R/Length 79/Prev 99077/Root 1274 0 R/Size 1304/Type/XRef/W[1 2 1]>>stream Proper shipping name is the standard technical name to describethe hazard properties and the composition of dangerous goods. [1] Appendix E: Schedule 2 - List of Dangerous Goods, 6 Registration, Approvals and Certification, 8 Manufacture and Modification of Tank Cars and Ton Containers for Transport of Dangerous Goods, 9 Qualifications and Maintenance of Tank Cars and Ton Containers, 10 Selection and Use of Containers for the Handling, Offering for Transport, or Transporting of Dangerous Goods by Rail, 11 Provisions for the One Time Movement of Non-Conforming Containers Presenting Low Safety Risks, Appendix A: Procedure - Liquefied Petroleum Gas Tank Car Emission Standard, Appendix B: Procedure - Anhydrous Ammonia Tank Car Emission Standard, Appendix C: Procedures for Tank-Head Puncture-Resistance Testing, Appendix D: Procedures for Simulated Pool-Fire and Torch-Fire Testing, Appendix E: Schedule 1 - Special Provisions, transportation-related measures and guidance, Methane, compressed or Natural gas, compressed, with high methane content, Methane, refrigerated liquid or natural gas, refrigerated liquid, with high methane content, Methylacetylene and propadiene mixture, stabilized, Dangerous Goods of Class2.1, not listed above, non-cryogenic, Ammonia solutions, relative density less than 0.880 at 15C (59F) in water, with more than 35% but not more than 50% ammonia, Dangerous Goods of Class2.2, not listed above, non-cryogenic, Ammonia solutions, relative density less than 0.880 at 15C (59F) in water, with more than 50% ammonia, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone B, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone C, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone D, Dinitrogen tetroxide, or Nitrogen dioxide, Ethylene oxide or Ethylene oxide, with nitrogen, Sulphur dioxide, liquefied or Sulphur dioxide, Dangerous Goods of Class2.3, not listed above, Dimethylhydrazine, symmetrical or 1,2-Dimethylhydrazine, Organochlorine pesticide, liquid, flammable, toxic, flash point less than 23C (73F), Petroleum sour crude oil, flammable, toxic, Dangerous Goods of Class 3, Packing Group I, not listed above, Ethanol and gasoline mixture, with more than 10 percent ethanol, Organochlorine pesticide, liquid, flammable, toxic, flashpoint less than 23C (73F), Dangerous Goods of Class 3, Packing Group II, not listed above, Elevated temperature liquid, flammable, n.o.s., with flash point above 60.5C (141F), at or above its flashpoint, Dangerous Goods of Class 3, Packing Group III, not listed above, Dangerous Goods of Class4.1, Packing Group I. Note 4: As the dangerous good is not identified with UN3373, the Category B mark is not required. (UN3291). (gasoline). :), How to Assign UN Packing Group for Dangerous Goods. Mercury is a naturally-occurring chemical element found in rock in the earth's crust, including in deposits of coal. N.O.S. The type of packages must be indicated by description of the package (for example, 12 drums). Being on this list does not mean Transport Canada or the TDG Directorate endorses or approves their services. Regs. entries are assigned with special provisions 274 or 318 (see column 6 in the example below). Some of the classes can be further divided into divisions, e.g., Class 1, while others do not have sub-divisions, e.g., Class 3. If you like this article, please share it. This mark is required when shipments meet the limited quantity exemption, and must be displayed on one side of a means of containment. WebEach subsidiary must be associated with at least one nexus. Flammable Gases 3. The picture below shows hazard symbols for Class 4 dangerous goods. If you have questions or need any help, please contact our sponsor. Figure 4: Placard requirements and placement for compartmentalized means of containment. Selecting a correct proper shipping name is not easy. 1. ), code or number for a particular hazard (e.g., 1- Explosive, 2 - Gases, 3 - Flammables), Provide quick identification of the dangerous goods in an emergency (e.g., release of dangerous goods during an incident), Communicate the nature and degree of the danger, Quickly determine if dangerous goods in a mixed load are incompatible, is determined to be a dangerous good under the TDG Regulations, and, displayed against a background of contrasting colour, made of durable, weather-resistant material that will resist coming detached or fade, Select the correct label(s) for each small means of containment (e.g., drum, package, overpack), Make sure that each small means of containment (e.g., package or container) of dangerous goods is properly labelled and marked, Select the correct placards and other safety marks for each large means of containment (e.g., tanker), Display the placards and other safety marks, or provide the appropriate placards to the carrier (when the means of containment or means of transport belongs to the carrier), Confirm that the safety marks are correct, Make sure the safety marks are displayed and remain displayed during transport, Replace safety marks when during transport they are stolen, lost, or defaced, Provide and display appropriate safety marks when the contents of the shipment change (e.g., new consignments are loaded on the means of transport), Remove or cover safety marks when the dangerous good is no longer present. 0400-20-10-.30 - 0400-20-10-.30 - PACKAGING AND TRANSPORTATION OF RADIOACTIVE MATERIAL. WebIdentification Product Name Mercury (Certified ACS) Cat No. For the dangerous goods other than Class 1 DG, a Conveyance Permit (For Dangerous Goods other than Class 1 Dangerous Goods) is required. Note 3: The containers inside the package not required to bear TDG safety marks. 28-35-189a - 28-35-189a - Advance notification of transport of nuclear waste, Kan. Admin. if applicable, the technical name of the dangerous goods, the classification of the dangerous goods, and. (iii) the primary class, which may be shown as a number only or under the heading Class or Classe or following the word Class or Classe. Please check if any of these measures apply to you. CCOHS is not liable for any loss, claim, or demand arising directly or indirectly from any use or reliance upon the information. Column 3 Class or Division Contains the class and, in the case of class 1, the division and compatibility group. Generally, if the shipment includes dangerous goods in Class 7, Radioactive Materials, then two labels are required on the small means of containment. It exists in several forms: Elemental (metallic) mercury. ), MARINE POLLUTANT. Gross quantity of Class 1.4 (except Class 1.4S) is 1000 kg or less, Class1.1, 1.2, 1.3 or 1.5 explosives that are not subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 10 kg, Class1.1, 1.2, 1.3 or 1.5 explosives that are subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 1000 articles. Mercury. Examples of such products are: 3. Products and These words must be displayed on a small or large means of containment when dangerous goods are shipped or imported for the hazard classes: Small means of containment: These words must be displayed next to the shipping name. hb```~ !o2)r10Dj`{0j@qz}]1%8Lt29+@b`t/c 9/fiF ~` C# Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. China and Kyrgyzstan are the main producers of mercury. For example, for a flammable mixture consisting of two or more alcohols, both entries below may be applicable. The primary class is the class of dangerous goods that takes precedence over any other class. See the images below for examples of how to place the dangerous goods placards on large means of containments such as a highway tank (Figure 3), and compartmentalized means of containment (Figure 4). ; UN 1992, FLAMMABLE LIQUID, TOXIC, N.O.S. If the product's name is listed in Schedule 1 or you located it by using the listed UN Number in Schedule 3, use the shipping name and its corresponding data (UN number, class, packing group/category) from that row. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers WebThe subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. Transportation of Dangerous Goods (TDG) - Classification, All It exists in three forms that have different properties, usage, and toxicity. Permanganates. ?O.Q\tF,"V4Iuu8jhb7ew?NI ~eS^lsEU_{\3>e; F]u:MvF7Bz3Jz;O>tzw5qy:!&|]&$fG6F`B@a'\` Eno14}tQ`?K4%1nFh,D_Qg4f>~j $7NH s:o~P;v4fRd%r{6|;>v&K >Z!O~X}u!wv=@~0}$vN=. Dangerous goods that can be shipped under this exemption will have a limited quantity index greater than 0 in Column 6(a) of Schedule 1 of the TDG Regulations. Code of Federal Regulations (49 CFR) (U.S. Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. This mark must be displayed on one side of a means of containment. The labels must be displayed on any side of the outer surface of a means of containment other than the side on which it is intended to rest or be stacked during transport. (b) Except as provided in this subpart, the basic description specified in paragraphs (a)(1), (2), (3), and (4) of this section must be shown in sequence with no additional information interspersed. The labels must be displayed on two opposite sides of the outer surface of a small means of containment. Some dangerous goods have multiple hazards. Please also see the following documents in this series: The purpose of dangerous goods safety marks is to: Dangerous goods safety marks are required when the good that is being transported: The TDG Regulations (Part 4) specify that all safety marks must be: Responsibilities for dangerous goods safety marks depend on whether the handler of the dangerous goods is the: Before the goods are loaded on the means of transport (i.e., vehicle, truck), the consignor or importer must: Misleading safety marks are dangerous goods safety marks that might be deceptive, ambiguous, or provide false information about the presence or nature of any dangers. 1273 0 obj <> endobj Mercury also combines with carbon to make organic mercury compounds. This placard is not mandatory, but it is permitted on a large means of containment (greater than 450 L) instead of any other placard when the containment has: - one or more dangerous goods that require different hazard class placards, - the dangerous goods are contained in two or more small means of containment, AND - the shipment consists of only the following dangerous goods classified in: NOTE: The TDG Regulations has specified circumstances when this placard is not allowed to be used. Figure 3: Placard requirement and placement for a single dangerous good transported in a highway tank Image from Transport Canada. There are 4 types of entries consisting of UN numbers and proper shipping names in the Dangerous Goods List. (d) Technical and chemical group names may be entered in parentheses between the proper shipping name and hazard class or following the basic description. 12 Va. Admin. Services Main Page. Azides. (b) for a liquefied petroleum gas that has not been odorized, the words Not Odourized or Not Odorized or Sans odorisant. If the dangerous goods are biohazardous substances (Class 6.2), the consignor may use the classification determined by Health Canada or the Canadian Food Inspection Agency. Special Provisions This column gives the special provisions that apply to the dangerous goods. EDT. Are safety marks required on consolidation bins? The flash point must be indicated for materials with a primary or subsidiary Class 3 hazard. See Section 4.23 of Part 4 in the TDG Regulations. Access to this website Except for combustible liquids, Substances (including substances and mixtures), and articles are assigned to one of the following 9 classes according to the most predominant hazards they pose in transport. Peroxides. Transportation of Dangerous Goods (TDG) - Dangerous Goods Safety Marks (Road), All Information on how to do the assignment is provided in Section 2.36 of Part 2. Subsection 2.2(4) and Parts 9 and 10 of the TDG Regulations authorize you to use the classification from the: Many substances in Schedule 1 are assigned one or more packing groups. size of the means of containment (e.g., small vs. large). For example, if you have a product for which you determined that the shipping name will be FLAMMABLE LIQUID, N.O.S. See Special Provision 34 in Schedule 2 of the TDG Regulations. However, if the dangerous goods are explosive, the consignor must use the classification determined by the Natural Resources Canada. For more details, consult the legislation directly. The Proper Shipping Name shall be supplemented with "MOLTEN"; Stabilized substances: Can I use a UN number that is not included in the Canadian TDG Regulations? As such, the mixture would be assigned the shipping name FLAMMABLE LIQUID, N.O.S.. (7) The number and type of packages must be indicated. (iv) for dangerous goods with a primary class of Class 1, Explosives, the compatibility group letter following the primary class. Ch. 6 CCR 1007-1 Part 17 - 6 CCR 1007-1 Part 17 - RADIATION CONTROL - TRANSPORTATION OF RADIOACTIVE MATERIALS, GA Reg. Meanwhile the actual assigned category is obtained from Appendix 3 in Part 2. Make sure the appropriate labels (TDG or Workplace Hazardous Materials Information System (WHMIS) are used in the workplace as required. View Past Newsletter, http://www.unece.org/fileadmin/DAM/trans/danger/publi/adr/adr2011/English/Part3.pdf, http://www.phmsa.dot.gov/filename/Marine_Pollutant_Guidance.pdf, Biocides and Biocidal Product Regulations, Example: UN 1133 ADHESIVES containing flammable liquids; UN 1263, PAINT, Example: UN 1987 ALCOHOLS, N.O.S. Dangerous Goods of Class4.2, Packing Group III, not listed above, Magnesium powder or Magnesium alloys, powder, Dangerous Goods of Class4.3, Packing Groups I, not listed above, Aluminum smelting by-products or Aluminum remelting by-products, Phosphorus pentasulphide, free from yellow and white phosphorus, Dangerous Goods of Class4.3, Packing Groups II, not listed above, Calcium cyanamide, with more than 0.1% Calcium carbide, Ferrosilicon, with 30% or more but less than 90% silicon, Magnesium granules, coated, particle size not less than 149mm, Dangerous Goods of Class4.3, Packing Group III, not listed above, Ammonium nitrate, liquid, hot concentrated solution, Hydrogen peroxide, stabilized or Hydrogen peroxide, aqueous solutions, stabilized, with more than 60% hydrogen peroxide, Dangerous Goods of Class5.1, Packing Group I, not listed above, Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water, Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts, Hydrogen peroxide, aqueous solution, with more than 40% but not more than 60% hydrogen peroxide, stabilized, as necessary, Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 40% hydrogen peroxide, stabilized, as necessary, Potassium nitrate and sodium nitrite mixture, Dangerous Goods of Class5.1, Packing Group II, not listed above, Dangerous Goods of Class5.1, Packing GroupII, Solids, not listed above, having no subsidiary class other than Class9, Dangerous Goods of Class5.1, Packing GroupIII, Liquids, Dangerous Goods of Class5.1, Packing GroupIII, Solids, Dangerous Goods of Class5.2, Packing GroupI, Dangerous Goods of Class5.2, Packing GroupII, Dangerous Goods of Class5.2, Packing GroupIII, Hydrocyanic acid, aqueous solution, with not more than 20% hydrogen cyanide, Hydrogen cyanide, solution in alcohol, with not more than 45 percent hydrogen cyanide, Hydrogen cyanide, stabilized, containing less than 3% water, Methyl bromide and ethylene dibromide mixture, liquid, Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23C (73F), Toxic by inhalation, liquid, n.o.s., with an LC, Toxic by inhalation, liquid, flammable, n.o.s., with an LC, Toxic by inhalation, liquid, water reactive, n.o.s., with an LC, Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC, Toxic by inhalation, liquid, corrosive, n.o.s., with an LC, Dangerous Goods of Class6.1, Packing GroupI, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupI, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, not listed above, with a subsidiary classification other than 9, Chlorosulphonic acid, with or without sulphur trioxide, Hydrazine, aqueous solution, with more than 37% hydrazine, by mass, Hydrazine, aqueous solution, flammable with more than 37% hydrazine, by mass, Hydrofluoric acid and sulphuric acid mixture, Hydrofluoric acid solution, more than 60% hydrogen fluoride, Nitrating acid mixtures, more than 50% nitric acid, Nitric acid, other than red fuming, with more than 70% nitric acid, Sulphuric acid, fuming, greater than or equal to 30% free sulphur trioxide, Sulphuric acid, fuming, less than 30% free sulphur trioxide, Dangerous Goods of Class8, Packing GroupI, not listed above, Battery fluid, acid or Sulphuric acid, with not more than 51% acid, Formic acid, with more than 85% acid by mass, Hydrofluoric acid solution, not more than 60% hydrogen fluoride, Nitrating acid mixtures, not more than 50% nitric acid, Nitric acid, other than red fuming, with not more than 70% nitric acid, Dangerous Goods of Class8, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class8, Packing GroupII, Solids, not listed above, Dangerous Goods of Class8, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class 8, Packing Group III, Solids, not listed above, Dangerous Goods of Class9, Packing GroupI, Liquids, Dangerous Goods of Class 9, Packing Group I, Solids, Blue asbestos (crocidolite) or Brown asbestos (amosite, mysorite), Dangerous Goods of Class9, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class 9, Packing Group II, Solids, not listed above. Download the OSH Answers app for free. Have the answers at your fingertips. If the dangerous goods are radioactive, the consignor must use the classification determined by the Canadian Nuclear Safety Commission. You can download all hazard symbols for all hazard classes above by clicking the picture below. WebChemical Classification: Inorganic substances Summary: Mercury combines with other elements, such as chlorine, sulfur, or oxygen, to form inorganic mercury compounds or "salts", which are usually white powders or crystals. Mercury and its compounds. For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. Indication of the packaging specification number (1H1) may be included in the description of the package (for example, 12 1H1 drums or 12 drums (UN 1A1)). Are the classifications for other modes or international shipments the same? You may experience longer than usual wait times or partial service interruptions. Chemical family name (e.g., alcohol, ketone, etc. Flammable solids 5. Note 2: Package certification safety marks are specified in the standard that the package or container is compliant with. UN Number This column gives the UN number assigned to the dangerous goods under the UN system. A substance, mixture, or article that is a marine pollutant and does not meet the classification criteria for inclusion in any other hazard class shall be declared under either UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, n.o.s. the other class that further identifies the hazards of the dangerous goods. Oxidizing 6. When are dangerous goods safety marks required? A label is used for a small means of containment whose capacity is 450 L or less. symbol (e.g., explosion, flames, corrosion, etc. The main product line is outboard motors. Yes. In addition -. Mixed Loads: dangerous good whose gross mass is 1000 kg or less, and there are at least two different dangerous goods, and the dangerous goods are contained in at least two small means of containment inside a large means of containment. From the surface of Mercury, the Sun would appear more than three times as large as it does when viewed from Earth, and the sunlight would be as much as seven times brighter. The term "MARINE POLLUTANT" shall be put in the end of dangerous goods descriptions. b) The laboratory test results show the product falls into one class and one packing group. This communication is accomplished by the: Note that the difference between labels and placards is their size. http://www.unece.org/fileadmin/DAM/trans/danger/publi/unrec/rev16/English/02E_Part2.pdf. (drazoxolon). Scheduled maintenance - Thursday, July 12 at 5:00 PM Alkalis. Note: The information below is provided as guidance only. Admin. (cadmium sulfide, isodecyl diphenyl phosphate), 9, III, Marine Pollutant. When the dangerous goods safety marks are, primary class label and each subsidiary class label for each of the dangerous goods, as well as the shipping name and UN number, must be displayed on the overpack, the word overpack is required on at least one side for overpacks with capacity less than 1.8 m3 (64 cubic feet), the words overpack on at least two opposite, required to display subsidiary hazard class placard. Self-heating solid, toxic, organic, n.o.s. The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. 120.790 - 120.790 - Advance Notification of Shipment of Nuclear Waste, 180 Neb. Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. The classification or shipping description is reported in the following order as per Part 3.5: (ii) the shipping name and, immediately after the shipping name unless it is already part of it, (a) for dangerous goods that are subject to special provision 16, the technical name, in parentheses, of at least one of the most dangerous substances that predominantly contributes to the hazard or hazards posed by the dangerous goods, and. 13 020 - 13-020 - ADVANCE NOTIFICATION OF TRANSPORT OF NUCLEAR WASTE, 10A NCAC 15 .0346 - 10A NCAC 15 .0346 - PREPARATION OF RADIOACTIVE MATERIAL FOR TRANSPORT. Go to Setup > company > Subsidiaries. The metal is obtained by heating cinnabar in a current of air and condensing the vapour. TN Rules and Regs. The three forms Identification number - UN Number must be displayed within a white rectangle located on the primary class label itself or next to the primary class. : AC413650000; AC413650025; AC413650050; AC413651000; AC413655000 CAS No 7783-35-9 Synonyms Mercuric sulfate The Primary class is shown first, with the subsidiary classes in brackets. Code DHS Sec. The size (i.e., capacity) of the means of containment itself also determines whether a label or placard is required. Regulations) for the transportation of dangerous goods by road. The class posing a lower hazard will be identified as a subsidiary class. It can also negatively affect reproductive health. a person capable of understanding the nature of the dangerous good (e.g., manufacturer's professional employees such as a chemical engineer, chemist, scientist, etc. Except for combustible liquids, the subsidiary hazard class(es) or subsidiary division number(s) must be entered in parentheses immediately following the primary hazard class or division number. Once the material has been tested at a laboratory, the test results are compared to the classification criteria in Part 2. For example: the mixture is liquid and homogeneous and the ingredients will not separate (e.g., no visible solids or two different phases such as you would observe when oil and water are mixed). It is determined according to the specification in section 2.8 and the Precedence of Classes Table which is provided in Part 2. That legal outcome opened the door to hire a new design and construction team to finish the North Course. International Civil Aviation Organization (ICAO) Technical Instructions for the transport of dangerous goods by air, International Maritime Dangerous Goods (IMDG) Code for the transport of dangerous goods by ship, or. The following provisions also apply: (i) For Class 1 materials, the quantity must be the net explosive mass. will be unavailable during this time.
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